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inert gas or steam The lean solvent then flows through the heat exchanger H1 to recover heat necessary for heating the reach solvent, passes the heat exchanger H2 to cool down to a desired temperature and finally enters the absorber [1] Usually, a small amount of fresh solvent should be added to the column in order to equalize the solvent loss due to evaporation in the desorber or underwent irreversible chemical reaction occurring in the whole system [1] Reactive absorption represents a process in which a selective solution of gaseous species by a liquid solvent phase is combined with chemical reactions As compared to purely physical absorption, reactive absorption does not necessarily require elevated pressure and high solubility of absorbed components: because of the chemical reaction, the equilibrium state can be shifted favorably, resulting in enhanced solution capacity [2].

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(12.10)

Most of the reactive absorption processes involve reactions in the liquid phase only, but in some of them both liquid and gas reactions occur [3, 4] Usually, the effect of chemical reactions in reactive absorption processes is advantageous only in the region of low gas-phase concentrations due to limitations by the reaction stoichiometry or equilibrium [5] Further difficulties of reactive absorption applications may be caused by the reaction heat through exothermic reactions and by relatively difficult solvent regeneration [6, 7] Most of the reactive absorption processes are steady-state operations, either homogeneously catalyzed or auto-catalyzed Recently, an application of a reactive absorption process based on using secondary amine groups on solid supports as immobilized activators has been reported [8] Reactive absorption processes are predominantly used for the production of basic chemicals, eg, sulfuric or nitric acids, and for the removal of harmful substances such as H2S from gas streams.

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Each customer may place multiple orders. While each order has its own unique OrderID primary key, the Order entity also has a foreign key attribute that contains the CustomerID of the customer who placed the order. The Order entity may have several tuples with the same CustomerID that de nes the relationship as one-to-many. A non-pro t organization has an annual pledge drive. As each donor makes an annual pledge, the pledges go into a secondary entity that can store an in nite number of years worth of pledges one tuple per year.

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Absorbers or scrubbers in which reactive absorption is performed are often considered as gas liquid reactors [9] If more attention is paid to the mass transport, these apparata are treated rather as absorption units Some important industrial applications of reactive absorption are given in Tab 91 Reactive absorption can be realized in a variety of equipment types The process is characterized by independent flow of both phases and permits both co-current (down-flow and up-flow) and countercurrent regimes Reactive absorption is essentially an old process which has been known since the foundation of modern industry This is also a very important process, being the basic operation in many technological chains More recently, the role of reactive absorption as a key environmental protection process has grown up significantly, and today the process appears to be the most widely applied reactive separation operation.

Documents can come to you in many different formats. Search just some of the Linux FTP sites on the Internet and you will find files in PostScript, DVI, man, PDF HTML, and TeX. There are , also a variety of graphics formats. Table 21-2 is a list of common document and graphics conversion utilities.

Despite the clear importance of reactive absorption, its behavior is still not properly understood This can be attributed to a very complex combination of process thermodynamics and kinetics, with intricate reaction schemes including ionic species, reaction rates varying over a wide range, and complex mass transfer reaction coupling As compared to distillation, reactive absorption is a fully rate-controlled process and it occurs definitely far from the equilibrium state Therefore, both practitioners and theoreticians are highly interested to establish a proper understanding and description of this process..

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